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These properties are analyzed by a procedure consisting of three steps: 0 Rigid molecules are oriented definitely: the oriented gas appt-ouch 0 Molecules as objects of static forces are deformed and reduce their symmetry: the site symmetry approach 0 All molecules within a unit cell couple dynamically: the factor group approurh Only for the interpretation of spectra of higher order or those of ionic crystals, semiconductors, or metals, the vibrational states of the whole crystal have to be regarded The factor group of a space group (Bhagavantam and Venkatarayudu, 1969) is simply the group of symmetry operators of a space group when the elementary translation operators are ignored; these do not contribute to the selection rules The factor group is found by taking the Schoenflies symbol of the space group and deleting the superscript, eg, D;: becomes D2h. 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One has to take into account, however, that the unit cell which is relevant for spectroscopy is the primitive (or Wigner-Seitz) unit cell It is a parallelepiped from which the entire lattice may be generated by applying multiples of elementary translations Face- and body-centered cells are multiple unit cells The content of such a cell has to be divided by a factor m to obtain the content of a primitive unit cell This factor rn is implicitly given by the international symbol for a space group: P and R denote primitive cells (rn = I), face-centered cells are denoted A, B , C (rn = 2), and F ( m = 4), and body-centered cells are represented by I (rn = 2) Examples are described by Turrell ( 1 972) The factor group of any space group is isomorphic to one of the 32 point groups. SUN SS2 RS/6000 RS/6000 SUN ss2 SMTP C PORT=2047 <OD><OA> SMTP R PORT=2047 250 Mail accepted <OD><OA> SMTP C PORT=2047 QUIT<OD><OA> SMTP R PORT=2047 22 1 csd-sun 1.csd.xxx.ca. csd.xxx.ca delivering mail ... 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